US 7,468,410 B2
Stabilization of polyolefins with liquid tris-(mono-alkyl)phenyl phosphites
Laura F. Chafin, Bologna (Italy); Walid Al-Akhdar, Mobile, Ala. (US); Sai Ping Shum, Pleasantville, N.Y. (US); Stanley J. Padegimas, Mobile, Ala. (US); and Roswell Easton King, Pleasantville, N.Y. (US)
Assigned to Ciba Specialty Chemicals Corporation, Tarrytown, N.Y. (US)
Filed on Jul. 17, 2006, as Appl. No. 11/487,839.
Claims priority of provisional application 60/701279, filed on Jul. 21, 2005.
Prior Publication US 2007/0021537 A1, Jan. 25, 2007
Int. Cl. C08K 5/524 (2006.01)
U.S. Cl. 524—128  [524/585; 524/587] 18 Claims
 
1. A process for stabilizing a polyolefin against the deleterious effects of melt processing, heat aging and exposure to combustion products-of natural gas, which process comprises
incorporating into or applying to said polyolefin
an effective stabilizing amount of a mixture of at least two different
tris-(mono-alkyl)phenyl phosphite esters of the formula l,

OG Complex Work Unit Drawing
where each R is the same or different and is a straight or branched chain alkyl of from 1 to 8 carbon atoms, and where said mixture of phosphite esters is in the liquid state at 25° C. and 1 atm of pressure.