US 7,468,405 B2
Increase in the melting point and the enthalpy of melting of polyamides by a water treatment
Jean-Philippe Allen, Irigny (France); Philippe Blondel, Bernay (France); and Patrick Douais, Le Noyer en Ouche (France)
Assigned to Atofina, Puteaux (France)
Filed on Oct. 22, 2003, as Appl. No. 10/689,840.
Claims priority of provisional application 60/425319, filed on Nov. 12, 2002.
Claims priority of application No. 02 13219 (FR), filed on Oct. 23, 2002.
Prior Publication US 2004/0138344 A1, Jul. 15, 2004
Int. Cl. C08F 6/24 (2006.01); C08F 6/00 (2006.01); C08J 3/28 (2006.01)
U.S. Cl. 523—328  [528/499; 528/503] 8 Claims
 
1. A method for increasing at least one of the following two parameters of a polyamide: (i) melting point and (ii) enthalpy of melting ΔHm, comprising:
contacting solid granular or powdered polyamide with a substance consisting of water, water containing methanol, or steam, at a temperature close to crystallization temperature Tc of the polyamide, for a time long enough to effect said increase;
separating water or steam from the polyamide and drying the polyamide.