US 7,468,092 B2
Operation of mixed conducting metal oxide membrane systems under transient conditions
Michael Francis Carolan, Allentown, Pa. (US)
Assigned to Air Products and Chemicals, Inc., Allentown, Pa. (US)
Filed on Apr. 27, 2005, as Appl. No. 11/115,778.
Application 11/115778 is a continuation in part of application No. 10/943574, filed on Sep. 17, 2004, granted, now 7,311,755.
Prior Publication US 2006/0060081 A1, Mar. 23, 2006
This patent is subject to a terminal disclaimer.
Int. Cl. B01D 53/22 (2006.01)
U.S. Cl. 95—54  [95/15; 95/19; 95/45; 96/4; 96/7; 96/11] 38 Claims
 
1. A method of operating an oxygen-permeable mixed conducting membrane comprising a dense layer of a mixed conducting metal oxide material, having an oxidant feed side, an oxidant feed surface, a permeate side, and a permeate surface, which method comprises controlling differential strain between the permeate surface and the oxidant feed surface at a value below a selected maximum value by varying oxygen partial pressure on either or both of the oxidant feed side and the permeate side of the oxygen-permeable mixed conducting membrane.