US 7,456,140 B2
Compositions for cleaning organic and plasma etched residues for semiconductor devices
Robert J. Small, Dublin, Calif. (US); Bakul P. Patel, Pleasanton, Calif. (US); Wai Mun Lee, Fremont, Calif. (US); Douglas Holmes, San Ramon, Calif. (US); Jerome Daviot, Antony (France); and Chris Reid, Glasgow (United Kingdom)
Assigned to EKC Technology, Inc., Hayward, Calif. (US)
Filed on Aug. 17, 2004, as Appl. No. 10/920,494.
Application 10/920494 is a continuation in part of application No. 09/903064, filed on Jul. 10, 2001, granted, now 6,777,380.
Claims priority of provisional application 60/217650, filed on Jul. 10, 2000.
Prior Publication US 2005/0202987 A1, Sep. 15, 2005
This patent is subject to a terminal disclaimer.
Int. Cl. C11D 7/50 (2006.01)
U.S. Cl. 510—175  [510/176; 134/1.3] 7 Claims
OG exemplary drawing
 
1. A method of removing a photoresist coating from a substrate comprising contacting the coating with an aqueous composition comprising
from about 0.5 percent by weight to about 3.5 percent by weight of ammonium bifluoride;
from about 15 percent by weight to about 70 percent by weight of an organic sulfoxide solvent selected from the group consisting of dimethyl sulfoxide, dipropyl sulfoxide, diethyl sulfoxide, methylethyl sulfoxide, diphenyl sulfoxide, methylphenyl sulfoxide, 1,1′-dihydroxyphenyl sulfoxide and mixtures thereof;
optionally a sulfone solvent corresponding to the following:

OG Complex Work Unit Drawing
where R1 and R2 are alkyl and R3-R10 are independently H or alkyl; and
from 0 to about 5 percent by weight of an alkanolamine;

OG Complex Work Unit Drawing
wherein:
the composition contains at least one of the alkanolamine and the sulfone solvent; when the sulfone solvent is present, it is present in an amount from about 30 percent by weight to about 50 percent by weight and the sulfone and the sulfoxide solvents are present in a combined amount of at least 55 percent by weight; and
when the sulfone solvent is not present, the sulfoxide solvent is present in an amount of at least about 55 percent by weight.