US 7,452,655 B2
Acrylic copolymer and radiation-sensitive resin composition
Hiroyuki Ishii, Tokyo (Japan); Kouichi Fujiwara, Tokyo (Japan); Hiroshi Yamaguchi, Tokyo (Japan); and Yukio Nishimura, Tokyo (Japan)
Assigned to JSR Corporation, Tokyo (Japan)
Appl. No. 10/533,254
PCT Filed Nov. 04, 2003, PCT No. PCT/JP03/14051
§ 371(c)(1), (2), (4) Date Oct. 25, 2005,
PCT Pub. No. WO2004/041879, PCT Pub. Date May 21, 2004.
Claims priority of application No. 2002-320697 (JP), filed on Nov. 05, 2002; and application No. 2002-330870 (JP), filed on Nov. 14, 2002.
Prior Publication US 2006/0074139 A1, Apr. 06, 2006
Int. Cl. G03F 7/00 (2006.01); G03F 7/004 (2006.01)
U.S. Cl. 430—270.1  [526/282] 12 Claims
 
1. An acrylic copolymer comprising:
a recurring unit of the following formula (1),

OG Complex Work Unit Drawing
a recurring unit of the following formula (2),

OG Complex Work Unit Drawing
wherein R represents a hydrogen atom or a methyl group; R1 individually represents a hydrogen atom, hydroxyl group, or —COOR3 group, wherein R3 is a hydrogen atom, a linear or branched alkyl group having 1-4 carbon atoms or an alicyclic alkyl group having 3-20 carbon atoms, provided that at least one of R1 groups is not a hydrogen atom, and
a recurring unit of the following formula (3),

OG Complex Work Unit Drawing
wherein any two of R2 groups form, in combination and together with the carbon atom to which the two R2 groups bond, a divalent alicyclic hydrocarbon group having 4-20 carbon atoms or a derivative thereof, with the remaining R2 being a linear or branched alkyl group having 1-4 carbon atoms, a monovalent alicyclic hydrocarbon group having 4-20 carbon atoms, or a derivative thereof.