US 11,814,543 B2
Corrosion protection for metallic substrates
William Weaver, Redcar (GB); Matthew David Sharp, Redcar (GB); and Gaven Johnson, Redcar (GB)
Assigned to APPLIED GRAPHENE MATERIALS UK LIMITED, Redcar (GB)
Appl. No. 16/967,709
Filed by APPLIED GRAPHENE MATERIALS UK LIMITED, Redcar (GB)
PCT Filed Feb. 6, 2019, PCT No. PCT/GB2019/050316
§ 371(c)(1), (2) Date Aug. 5, 2020,
PCT Pub. No. WO2019/155201, PCT Pub. Date Aug. 15, 2019.
Claims priority of application No. 1801931 (GB), filed on Feb. 6, 2018.
Prior Publication US 2021/0040331 A1, Feb. 11, 2021
This patent is subject to a terminal disclaimer.
Int. Cl. C09D 5/08 (2006.01); C08K 3/04 (2006.01); B82Y 30/00 (2011.01); C09D 7/61 (2018.01); C09D 163/00 (2006.01); C01B 32/158 (2017.01); C01B 32/194 (2017.01); C09D 7/40 (2018.01); C09D 7/62 (2018.01); B05D 7/14 (2006.01); C09D 5/24 (2006.01); C23C 28/04 (2006.01)
CPC C09D 5/084 (2013.01) [B05D 7/14 (2013.01); C01B 32/158 (2017.08); C01B 32/194 (2017.08); C08K 3/042 (2017.05); C09D 5/24 (2013.01); C09D 7/62 (2018.01); C09D 7/66 (2018.01); C09D 7/69 (2018.01); C09D 7/70 (2018.01); C09D 163/00 (2013.01); C23C 28/04 (2013.01); B05D 2202/25 (2013.01); B82Y 30/00 (2013.01); C01B 2204/04 (2013.01); C01B 2204/22 (2013.01); C01B 2204/32 (2013.01); C01P 2004/24 (2013.01); C01P 2004/64 (2013.01)] 13 Claims
 
1. A coating system for coating a metallic substrate that is susceptible to corrosion, the coating system being for creation of a first coating on the metallic substrate, and, subsequently, a second coating over the first coating, the coating system comprising a first composition and a second composition, wherein the first coating is formed from the first composition and the second coating is formed from the second composition; the first composition is suitable for applying the first coating to the metallic substrate, and is characterised in that the first composition comprises a carrier medium and graphene platelets, in which the first coating comprises between 0.002 wt % and 0.009 wt % of the graphene platelets, and the graphene platelets comprise one of or a mixture of graphene nanoplates and/or graphite flakes in which the graphite flakes have one nanoscale dimension and 25 or less layers, wherein more than 50% of the graphene platelets have an electrical conductivity greater than 2.15×107 S/m at 20° C., and the carrier medium is an electrical insulator; and the second composition comprises a carrier medium and graphitic platelets in which the second coating comprises more than 0.1 wt % of the graphitic platelets, and in which more than 50% of the graphitic platelets of the second coating have an electrical conductivity of less than 2.0×10−5 S/m at 20° C.