CPC C06B 35/00 (2013.01) [C01G 29/00 (2013.01); C06B 41/00 (2013.01); C06B 43/00 (2013.01); C06C 7/00 (2013.01); C07F 9/94 (2013.01); B60R 2021/26029 (2013.01); C06C 9/00 (2013.01)] | 9 Claims |
1. A method for preparation of energetic compounds based on bismuth salts with reduced toxicity, having properties of primary explosives, said method comprising:
preparing a suspension of soluble bismuth perchlorates by a reaction of bismuth oxide and perchloric acid;
reacting said soluble bismuth perchlorates with water to form a solution; reacting said solution with soluble salts of organic or inorganic energetic compounds by a metathetical reaction forming a precipitate of bismuth energetic compounds;
wherein the soluble salts of the organic or inorganic energetic compounds are based on azides, aromatic polynitro compounds, or derivatives thereof, or nitrogenous heterocyclic compounds, thereby forming a bismuth salt having a bismuth cation selected from the group consisting of Bi(3+), BiO(+), Bi(OH)2(+), Bi(OH)(2+), (BiO)5OH(4+), and Bi6O4(OH)4(6+) and an anion selected from the group consisting of inorganic azides, polynitro-phenols, polynitro-azido-phenols, derivatives of polynitro-diazo-chinones, polynitro-furoxanes and five-membered nitrogenous heterocycles or derivatives thereof.
|