US 11,807,696 B2
Method for producing dicyclopentadiene-based resin
Hyeonuk Kang, Daejeon (KR); Pilje Seong, Daejeon (KR); Kyongjun Yoon, Daejeon (KR); Min Ho Lee, Daejeon (KR); and Heejin Jang, Daejeon (KR)
Assigned to HANWHA SOLUTIONS CORPORATION, Seoul (KR)
Appl. No. 16/973,509
Filed by HANWHA SOLUTIONS CORPORATION, Seoul (KR)
PCT Filed May 14, 2019, PCT No. PCT/KR2019/005767
§ 371(c)(1), (2) Date Dec. 9, 2020,
PCT Pub. No. WO2019/240386, PCT Pub. Date Dec. 19, 2019.
Claims priority of application No. 10-2018-0066679 (KR), filed on Jun. 11, 2018.
Prior Publication US 2021/0246231 A1, Aug. 12, 2021
Int. Cl. C08F 2/01 (2006.01); C08F 232/08 (2006.01)
CPC C08F 2/01 (2013.01) [C08F 232/08 (2013.01); C08F 2500/02 (2013.01); C08F 2500/25 (2013.01)] 9 Claims
 
1. A method for producing a dicyclopentadiene-based resin, the method comprising:
a) a primary thermal polymerization step of thermally polymerizing a monomer composition in a continuous stirred tank reactor (CSTR) under non-catalytic conditions, the monomer composition containing a mixed monomer of dicyclopentadiene and a C2-C20 olefin-based monomer, or a mixed monomer of dicyclopentadiene, a C2-C20 olefin-based monomer, and an aromatic vinyl-based monomer; and
b) a secondary thermal polymerization step of thermally polymerizing a reaction product obtained by the primary thermal polymerization in a plug flow reactor (PFR) under non-catalytic conditions.