US 7,588,794 B2
Coatings for drug delivery devices based on poly (orthoesters)
Stephen D. Pacetti, San Jose, Calif. (US)
Assigned to Advanced Cardiovascular Systems, Inc., Santa Clara, Calif. (US)
Filed on Sep. 21, 2007, as Appl. No. 11/859,372.
Application 11/859372 is a continuation of application No. 10/382197, filed on Mar. 04, 2003, granted, now 7,288,609.
Prior Publication US 2008/0071027 A1, Mar. 20, 2008
Int. Cl. A61F 2/06 (2006.01); A61F 2/00 (2006.01); C08G 2/00 (2006.01); C08G 65/48 (2006.01); C08G 4/00 (2006.01)
U.S. Cl. 427—2.1  [427/2.24; 427/2.25; 525/54.21; 525/54.24; 525/58; 525/60; 525/63; 525/88; 525/92 A; 525/92 L; 525/410; 525/415; 525/418; 525/419; 525/420; 525/434; 525/437; 525/439; 525/450; 525/453; 525/454; 525/474; 525/479; 623/1.15; 623/1.39] 23 Claims
 
1. A coating for a medical device comprising: a block copolymer and another polymer, wherein the block copolymer has
a first block comprising a soft segment having a Tg below 37° C. wherein the soft segment is a reaction product of a spirodiketene acetal and a non-fouling moiety selected from the group consisting of a poly(alkylene glycol), poly(ethylene oxide-co-propylene oxide) (PLURONIC®), hydroxylated poly(vinyl pyrrolidone), dextran, dextrin, hyaluronic acid and derivatives thereof, poly(2-hydroxyethyl methacrylate) and mixtures thereof; and,
a second block comprising a hard segment having a Tg above 37° C. wherein the hard segment is a reaction product of a spirodiketene acetal and a diol selected from the group consisting of a C2-C16 alkylene glycol, a cycloaliphatic diol, a cyclohexanedimethanol, an oligoalkylene glycol.