US 7,588,702 B2
Method of quenching electronic excitation of chromophore-containing organic molecules in photoactive compositions
Craig A. Bonda, Winfield, Ill. (US); and Anna Pavlovic, Elmwood Park, Ill. (US)
Assigned to Hallstar Innovations Corp., Chicago, Ill. (US)
Filed on Jan. 30, 2008, as Appl. No. 12/22,758.
Application 12/022758 is a continuation in part of application No. 11/891281, filed on Aug. 09, 2007.
Prior Publication US 2009/0041847 A1, Feb. 12, 2009
This patent is subject to a terminal disclaimer.
Int. Cl. F21V 9/04 (2006.01); F21V 9/06 (2006.01); G02B 5/22 (2006.01); G02B 5/26 (2006.01)
U.S. Cl. 252—589  [424/59; 424/60; 424/401; 514/520; 524/90; 558/410] 12 Claims
 
1. A method of increasing the UV absorbing life of a sunscreen composition containing (a) a dibenzoylmethane derivative that reaches a singlet excited state or fluoresces when exposed to UV radiation and (b) a cinnamate ester comprising adding a compound of formula (I) in an amount effective to quench the singlet excited state energy from the dibenzoylmethane derivative and transfer the singlet excited state energy from the dibenzoylmethane derivative to the compound of formula (I) thereby returning the dibenzoylmethane derivative to its ground state so that the dibenzoylmethane derivative can absorb more photons from ultraviolet light before it undergoes a photochemical reaction destructive to its UV-absorbing capability thereby photostabilizing (a) and (b)

OG Complex Work Unit Drawing
wherein one of R1 and R2 is a straight or branched chain C1-C30 alkoxy radical, and the non-alkoxy R1 or R2 is hydrogen; and R3 is a straight or branched chain C1-C30 alkyl radical.