| US 7,585,981 B2 | ||
| Method for producing trimer of indole derivative, and trimer of indole derivative and laminated structure thereof | ||
| Shinichi Maeda, Yokohama (Japan); Fumino Momose, Otake (Japan); Yoshikazu Saitoh, Yokohama (Japan); and Takashi Saitoh, Yokohama (Japan) | ||
| Assigned to Mitsubishi Rayon Co., Ltd., Tokyo (Japan) | ||
| Filed on May 22, 2006, as Appl. No. 11/437,581. | ||
| Application 11/437581 is a division of application No. 10/399449, granted, now 7,115,751, previously published as PCT/JP01/08442, filed on Sep. 27, 2001. | ||
| Claims priority of application No. 2000-317045 (JP), filed on Oct. 17, 2000; and application No. 2001-159604 (JP), filed on May 28, 2001. | ||
| Prior Publication US 2006/0211793 A1, Sep. 21, 2006 | ||
| Int. Cl. C07D 209/56 (2006.01) | ||
| U.S. Cl. 548—416 [548/455] | 36 Claims |
1. An indole derivative trimer of following formula (3):
![]() wherein R1 to R12 are substituents each independently selected from the group consisting of hydrogen, linear or branched alkyl group having
1 to 24 carbon atoms, linear or branched alkoxy group having 1 to 24 carbon atoms, linear or branched acyl group having 2
to 24 carbon atoms, aldehyde group, carboxyl group, linear or branched carboxylic ester group having 2 to 24 carbon atoms,
sulfonic group, linear or branched sulfonic ester group having 1 to 24 carbon atoms, cyano group, hydroxyl group, nitro group,
amino group, amide group, and halogen group, providing that the cases where all of R1 to R12 are hydrogen and where all of R2, R6 and R10 are substituted by the same substituent and the rest of the substituents are all hydrogen are excluded;
Xa− is at least one anion selected from the group of monovalent to tervalent anions consisting of chlorine ion, bromine ion,
iodine ion, fluorine ion, nitrate ion, sulfate ion, hydrogen sulfate ion, phosphate ion, fluoroborate ion, perchlorate ion,
thiocyanate ion, acetate ion, propionate ion, methane sulfonate ion, p-toluene sulfonate ion, trifluoroacetate ion, and trifluoeomethane
sulfonate ion;
a is an integral number in the range from 1 to 3 indicating the ionic valence of the ion X; and
m is a number in the range from 0.001 to 0.5.
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