US 7,585,432 B2
High density cobalt-manganese coprecipitated nickel hydroxide and process for its production
Hiroyuki Ito, Fukui (Japan); Takeshi Usui, Fukui (Japan); Mamoru Shimakawa, Fukui (Japan); and Toyoshi Iida, Fukui (Japan)
Assigned to Tanaka Chemical Corporation, Fukui-Ken (Japan)
Filed on Nov. 10, 2004, as Appl. No. 10/985,778.
Application 10/985778 is a division of application No. 10/003916, filed on Nov. 02, 2001, abandoned.
Claims priority of application No. 2000-337873 (JP), filed on Nov. 06, 2000.
Prior Publication US 2005/0089756 A1, Apr. 28, 2005
Int. Cl. H01M 4/32 (2006.01); C01G 53/04 (2006.01)
U.S. Cl. 252—500  [252/182.1; 252/518.1; 429/223; 429/224; 429/206; 423/599; 423/594] 7 Claims
OG exemplary drawing
 
1. A process for production of high density cobalt-manganese coprecipitated nickel hydroxide particles for use in lithium ion batteries, wherein said particles are represented by the formula:
(Ni(1−x−y)CoxMny)(OH)2
wherein 1/10≤x≤⅓ and 1/20≤y≤⅓;said process comprising the steps of:
continuously supplying an aqueous solution of a nickel salt which contains a cobalt salt and a manganese salt, a complexing agent, and an alkali metal hydroxide into a reactor either in an inert gas atmosphere or in the presence of a reducing agent;
continuously growing crystals of said particles; and
continuously removing crystals of said particles from said reactor.