US 7,583,058 B2
Method of charging lithium ion secondary battery including a constant current, charging apparatus, and power supply apparatus
Tsuyoshi Iijima, Chuo-ku (Japan); Kazuya Ogawa, Chuo-ku (Japan); Toshifumi Tanaka, Chuo-ku (Japan); and Satoshi Maruyama, Chuo-ku (Japan)
Assigned to TDK Corporation, Tokyo (Japan)
Filed on Nov. 15, 2004, as Appl. No. 10/986,956.
Claims priority of application No. 2003-390858 (JP), filed on Nov. 20, 2003.
Prior Publication US 2005/0194934 A1, Sep. 08, 2005
Int. Cl. H02J 7/00 (2006.01)
U.S. Cl. 320—128  [320/107; 429/231.1] 14 Claims
OG exemplary drawing
 
1. A method of charging a lithium ion secondary battery, the lithium ion secondary battery comprising 1) a positive electrode that includes a mixed metal oxide containing at least Li, Mn, and Ni as metal components as a positive electrode active material, 2) a negative electrode, and 3) a nonaqueous electrolytic solution containing a lithium salt, the method comprising:
constant current charging the lithium ion secondary battery with a set charging current value I1 corresponding to a set value nC satisfying a condition represented by an expression (1):
10C<nC≤60C  (1)
where C is a rated capacity value of the lithium ion secondary battery, and n is a number from 2 to 60, wherein
the mixed metal oxide simultaneously satisfies conditions of expressions (I) to (IV):
LixMnyNizCo(1-y-z)O2  (I)
0.85≤X≤1.1  (II)
0.1≤Y≤0.5  (III)
0.55≤Z≤0.8  (IV)
where X, Y, and Z in expression (I) indicate values simultaneously satisfying the conditions of expressions (II) to (IV).