US 7,579,115 B2
Gelling agent for alkaline battery and alkaline battery
Kazuya Ohtani, Kyoto (Japan); and Takeaki Yamaguchi, Kyoto (Japan)
Assigned to Sanyo Chemical Industries, Ltd., Kyoto (Japan)
Appl. No. 11/631,651
PCT Filed Jul. 06, 2005, PCT No. PCT/JP2005/012503
§ 371(c)(1), (2), (4) Date Jan. 05, 2007,
PCT Pub. No. WO2006/006471, PCT Pub. Date Jan. 19, 2006.
Claims priority of application No. 2004-201441 (JP), filed on Jul. 08, 2004.
Prior Publication US 2007/0231703 A1, Oct. 04, 2007
Int. Cl. H01M 6/14 (2006.01); H01M 10/26 (2006.01)
U.S. Cl. 429—300  [429/188; 429/189; 429/206] 11 Claims
OG exemplary drawing
 
1. A gelling agent for use in an alkaline battery, the gelling agent comprising a cross-linked polymer (A) formed with a (meth)acrylic acid (salt) as a principal constituent monomer unit,
wherein the gelling agent allows an obtained gel (GA) to have a viscosity ratio (N1/N60), determined as follows, of 0.7 to 1.3, and includes components soluble in 37 wt % aqueous solution of potassium hydroxide that account for 30 wt % or less of the gelling agent:
the viscosity ratio (N1/N60) of the gel (GA) is determined by preparing the gel (GA) by stirring 100 parts by weight of 37 wt % aqueous solution of potassium hydroxide, 2 parts by weight of the cross-linked polymer (A), and 200 parts by weight of zinc powder at 40° C. so as to be mixed uniformly, and measuring a viscosity (40° C., N1) of the gel (GA) after being left to stand at the same temperature for one day, and a viscosity (40° C., N60) of the gel (GA) after being left to stand at the same temperature for sixty days, according to JIS K7117-1: 1999, and
wherein the cross-linked polymer (A) includes a cross-linking agent (b) unit that is decomposed by hydrolysis in an alkaline environment, and a cross-linking agent (c) unit that is not decomposed by hydrolysis in an alkaline environment.