US 7,553,998 B2
Energy-efficient process for para-xylene production
Leo Bresler, Northbrook, Ill. (US); and Robert B. Larson, Chicago, Ill. (US)
Assigned to UOP LLC, Des Plaines, Ill. (US)
Filed on Jun. 21, 2006, as Appl. No. 11/425,531.
Prior Publication US 2007/0299289 A1, Dec. 27, 2007
Int. Cl. C07C 5/27 (2006.01); C07C 4/12 (2006.01)
U.S. Cl. 585—319  [585/470; 585/488; 585/480; 585/481] 6 Claims
OG exemplary drawing
 
1. A process for the production and recovery of one or more high-purity xylene isomers from a catalytic reformate, comprising the sequential steps of:
(a) fractionating the catalytic reformate to obtain a light reformate and a heavy-reformate feed stream comprising alkylaromatic hydrocarbons and containing about 1.0 wt.-% or more of C9 and heavier hydrocarbons including about 0.5 wt.-% or more of methylethylbenzenes;
(b) contacting the feed stream in the presence of hydrogen with a heavy-aromatics-conversion catalyst in a heavy-aromatics-conversion zone at heavy-aromatics-conversion conditions to obtain a de-ethylated stream having a lower content of methylethylbenzenes than the content in the feed stream;
(c) fractionating the de-ethylated aromatic stream to separate a light product comprising C7 and lighter hydrocarbons and a heavy product comprising C9 and heavier hydrocarbons from a intermediate stream comprising C8 aromatics;
(d) subjecting the light reformate stream to an aromatics-extraction and fractionation step to separate benzene, toluene and a toluene-bottoms stream from a non-aromatic raffinate;
(e) contacting the heavy product comprising C9 and heavier hydrocarbons and at least a portion of the toluene in a transalkylation zone with a transalkylation catalyst at transalkylation conditions to obtain a transalkylation product;
(f) fractionating the transalkylation product to separate a C7 and lighter stream, an intermediate stream and a C9 and heavier stream;
(g) subjecting at least a portion of the intermediate stream, along with an isomerized stream, to an isomer-recovery process to recover at least one high-purity xylene isomer and yield a C8-aromatic raffinate stream comprising non-recovered C8-aromatic isomers; and,
(h) contacting at least a portion of the C8-aromatic raffinate stream with an isomerization catalyst in an isomerization zone at isomerization conditions comprising substantially less than 0.05 moles of hydrogen/mole of feed to obtain the isomerized stream comprising a concentration of at least one xylene isomer that is higher than the concentration in the C8-aromatic raffinate stream.