| US 7,553,794 B2 | ||
| Heteropolyacid and or its salt supported catalyst, production process of the catalyst and production process of compound using the catalyst | ||
| Masaaki Sakai, Oita (Japan) | ||
| Assigned to Showa Denko K.K., Tokyo (Japan) | ||
| Appl. No. 10/539,706 PCT Filed Nov. 27, 2003, PCT No. PCT/JP03/15186 § 371(c)(1), (2), (4) Date Jun. 17, 2005, PCT Pub. No. WO2004/056474, PCT Pub. Date Jul. 08, 2004. |
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| Claims priority of provisional application 60/436633, filed on Dec. 30, 2002. | ||
| Claims priority of application No. 2002-369424 (JP), filed on Dec. 20, 2002. | ||
| Prior Publication US 2006/0052240 A1, Mar. 09, 2006 | ||
| Int. Cl. B01J 23/00 (2006.01); B01J 21/18 (2006.01); B01J 21/02 (2006.01); B01J 27/00 (2006.01); B01J 27/198 (2006.01); B01J 27/19 (2006.01); B01J 21/00 (2006.01); B01J 23/02 (2006.01); B01J 23/06 (2006.01); C01B 15/16 (2006.01); C01B 25/26 (2006.01); C01B 15/14 (2006.01); C01B 33/20 (2006.01); C07C 69/74 (2006.01); C07C 61/00 (2006.01); C07C 61/08 (2006.01); C07C 51/245 (2006.01) | ||
| U.S. Cl. 502—300 [502/180; 502/182; 502/204; 502/206; 502/208; 502/209; 502/210; 502/211; 502/232; 502/240; 502/247; 502/248; 502/254; 502/255; 502/340; 502/349; 502/350; 502/353; 423/305; 423/306; 423/307; 423/325; 423/326; 560/1; 562/400; 562/523] | 16 Claims |

| 1. A supported catalyst comprising a support having a support surface, and supported on the support at least one member selected from the group consisting of heteropolyacids and heteropolyacid salts, wherein 90 mass % or more of the heteropolyacid and/or heteropolyacid salt is present in a surface layer region that extends from the support surface to a distance from the support surface of 30% toward the midpoint in a cross section of the support. |