US 7,553,337 B2
Hair colorants for simultaneous dyeing and brightening of keratin fibers
Cecile Pasquier, Marly (Switzerland); Caroline Kiener, Marly (Switzerland); and Hans-Juergen Braun, Ueberstorf (Switzerland)
Assigned to Wella AG, Darmstadt (Germany)
Appl. No. 10/587,763
PCT Filed Nov. 16, 2005, PCT No. PCT/EP2004/012982
§ 371(c)(1), (2), (4) Date Jul. 28, 2006,
PCT Pub. No. WO2005/079732, PCT Pub. Date Sep. 01, 2005.
Claims priority of application No. 10 2004 008 604 (DE), filed on Feb. 21, 2004.
Prior Publication US 2007/0169284 A1, Jul. 26, 2007
This patent is subject to a terminal disclaimer.
Int. Cl. A61Q 5/10 (2006.01); C09B 44/08 (2006.01)
U.S. Cl. 8—405  [8/406; 8/437; 8/455; 8/466; 8/570; 8/571; 8/575; 534/604] 12 Claims
 
1. An agent for the simultaneous brightening and coloring of keratin fibers, wherein the agent contains an oxidant and at least one thiazolium dye of formula (I) and has a basic pH

OG Complex Work Unit Drawing
wherein
R1 stands for a saturated or unsaturated (C1-C12)-alkyl group, a halogen atom-substituted (C1-C12)-alkyl group, a hydroxy-(C1-C12)-alkyl group, a (C1-C6)-alkoxy-(C1-C12)-alkyl group, an amino-(C1-C12)-alkyl group, a (C1-C6)-alkylamino-(C1-C12)-alkyl group, a di(C1-C6)-alkylamino-(C1-C12)-alkyl group, a cyano-(C1-C12)-alkyl group, a substituted or unsubstituted phenyl group or a substituted or unsubstituted benzyl group;
R2 and R3 can be equal or different and independently of each other stand for hydrogen, a halogen atom, a saturated or unsaturated (C1-C12)-alkyl group, a (C1-C12)-alkoxy group, a nitro group, an amino group, a (C1-C12)-alkylamino group, a di(C1-C12)-alkylamino group, a (C1-C12)-hydroxyalkylamino group, a di(C1-C12)-hydroxyalkylamino group, a substituted or unsubstituted phenyl group or a substituted or unsubstituted heteroaryl group;
R4 stands for hydrogen, a saturated or unsaturated (C1-C12)-alkyl group, a halogen atom-substituted (C1-C12)-alkyl group, a hydroxy-(C1-C12)-alkyl group, an amino-(C1-C12)-alkyl group or a benzyl group;
R5 and R6 can be equal or different and independently of each other stand for hydrogen, a halogen atom, a saturated or unsaturated (C1-C12)-alkyl group, a hydroxyl group, a (C1-C12)-alkoxy group, a cyano group, a nitro group, an amino group, a (C1-C12)-alkylamino group or a di(C1-C12)-alkylamino group and
A stands for an anion of an organic or inorganic acid.