US 7,550,640 B2
High viscosity PAOs based on 1-decene/1-dodecene
Phil Surana, Somerset, N.J. (US); Norman Yang, Westfield, N.J. (US); and Pramod J. Nandapurkar, Plainsboro, N.J. (US)
Assigned to ExxonMobil Chemical Patents Inc., Houston, Tex. (US)
Filed on Jan. 14, 2005, as Appl. No. 11/36,904.
Prior Publication US 2006/0161034 A1, Jul. 20, 2006
Int. Cl. C07C 2/08 (2006.01)
U.S. Cl. 585—532  [585/520; 585/530] 9 Claims
 
1. A process for producing a polyalphaolefin (PAO) comprising contacting a feed consisting of 40-60 wt. % 1-decene and 60-40 wt. % 1-dodecene with an oligomerization catalyst in an oligomerization reaction zone under oligomerization conditions for a time sufficient to produce either a PAO having a kinematic viscosity of about 40 cSt at 100° C. (ASTM D-445), a viscosity index of at least about 150 (ASTM D-2270), and a pour point of less than or equal to about −42° C. (ASTM D-97), or a PAO having a kinematic viscosity of about 100 cSt at 100° C. (ASTM D-445), a viscosity index of at least about 170 (ASTM D-2270), and a pour point of less than or equal to about −30° C. (ASTM D-97), wherein the PAO has a number average molecular weight of from about 1200 to about 4000 wherein said oligomerization catalyst is selected from the group consisting of AlCl3, AlBr3, and mixtures thereof.