US 7,550,534 B2
Thermoplastic method, composition, and article
Xinyu Zhao, Houston, Tex. (US); Vijay Mhetar, Slingerlands, N.Y. (US); and Thomas J. Hartle, Delmar, N.Y. (US)
Assigned to Sabic Innovative Plastics IP B.V., (Netherlands)
Filed on Nov. 16, 2005, as Appl. No. 11/281,306.
Prior Publication US 2007/0112132 A1, May 17, 2007
Int. Cl. C08L 53/02 (2006.01)
U.S. Cl. 525—88  [525/98; 525/99] 13 Claims
 
1. A method of preparing a thermoplastic composition, comprising:
melt kneading a thermoplastic vulcanizate and a first hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene to form a vulcanizate-copolymer blend; and
melt kneading the vulcanizate-copolymer blend, a poly(arylene ether), and a second hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene;
wherein the thermoplastic vulcanizate comprises a crystalline or semi-crystalline thermoplastic polyolefin; and a dynamically partially vulcanized rubber selected from ethylene-propylene copolymers, ethylene-propylene-diene terpolymers, styrene butadiene rubber, nitrile butadiene rubber, isobutene-isoprene rubber, styrene-(ethylene-styrene)-butadiene block copolymers, butyl rubber, isobutylene-p-methylstyrene copolymers, brominated isobutylene-p-methylstyrene copolymers, natural rubber, and combinations thereof;
wherein the first hydrogenated block copolymer and the second hydrogenated block copolymer are each independently a styrene-(ethylene-butylene)-styrene triblock copolymer;
wherein the poly(arylene ether) comprises 2,6-dimethyl-1,4-phenylene ether units;
wherein the vulcanizate-copolymer blend comprises a dispersed phase having a mean particle size, measured along a major axis, of about 0.1 to about 3 micrometers; and
wherein the thermoplastic composition comprises a dispersed phase having a mean particle size, measured along a major axis, of about 1 to about 3 micrometers.