| US 7,550,534 B2 | ||
| Thermoplastic method, composition, and article | ||
| Xinyu Zhao, Houston, Tex. (US); Vijay Mhetar, Slingerlands, N.Y. (US); and Thomas J. Hartle, Delmar, N.Y. (US) | ||
| Assigned to Sabic Innovative Plastics IP B.V., (Netherlands) | ||
| Filed on Nov. 16, 2005, as Appl. No. 11/281,306. | ||
| Prior Publication US 2007/0112132 A1, May 17, 2007 | ||
| Int. Cl. C08L 53/02 (2006.01) | ||
| U.S. Cl. 525—88 [525/98; 525/99] | 13 Claims |
| 1. A method of preparing a thermoplastic composition, comprising:
melt kneading a thermoplastic vulcanizate and a first hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated
diene to form a vulcanizate-copolymer blend; and
melt kneading the vulcanizate-copolymer blend, a poly(arylene ether), and a second hydrogenated block copolymer of an alkenyl
aromatic compound and a conjugated diene;
wherein the thermoplastic vulcanizate comprises a crystalline or semi-crystalline thermoplastic polyolefin; and a dynamically
partially vulcanized rubber selected from ethylene-propylene copolymers, ethylene-propylene-diene terpolymers, styrene butadiene
rubber, nitrile butadiene rubber, isobutene-isoprene rubber, styrene-(ethylene-styrene)-butadiene block copolymers, butyl
rubber, isobutylene-p-methylstyrene copolymers, brominated isobutylene-p-methylstyrene copolymers, natural rubber, and combinations
thereof;
wherein the first hydrogenated block copolymer and the second hydrogenated block copolymer are each independently a styrene-(ethylene-butylene)-styrene
triblock copolymer;
wherein the poly(arylene ether) comprises 2,6-dimethyl-1,4-phenylene ether units;
wherein the vulcanizate-copolymer blend comprises a dispersed phase having a mean particle size, measured along a major axis,
of about 0.1 to about 3 micrometers; and
wherein the thermoplastic composition comprises a dispersed phase having a mean particle size, measured along a major axis,
of about 1 to about 3 micrometers.
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