US 7,541,507 B2
Oligomerization and catalysts therefor
Jihad Mohammed Dakka, Whitehouse Station, N.J. (US); Hans K. T. Goris, Laakdal (Belgium); Georges M. K. Mathys, Bierbeek (Belgium); Roger Eijkhoudt, GC Breda (Netherlands); Marc P. H. Puttemans, Dilbeek (Belgium); and Stephen Harold Brown, Brussels (Belgium)
Assigned to Exxonmobil Chemical Patents Inc., Houston, Tex. (US)
Filed on Jan. 09, 2007, as Appl. No. 11/651,160.
Application 11/651160 is a continuation of application No. 10/492705, granted, now 7,186,874, previously published as PCT/GB02/04776, filed on Oct. 23, 2002.
Claims priority of application No. 01309013 (EP), filed on Oct. 24, 2001; and application No. 01309032 (EP), filed on Oct. 24, 2001.
Prior Publication US 2007/0191654 A1, Aug. 16, 2007
This patent is subject to a terminal disclaimer.
Int. Cl. C07C 2/02 (2006.01)
U.S. Cl. 585—533  [585/502; 585/520] 6 Claims
 
1. In a process for the oligomerization of olefins comprising contacting a feed containing olefin monomers with at least one oligomerization catalyst having the TON and/or MFS structure under oligomerization conditions, including a reaction temperature, to produce a product selected from the group consisting of dimers, trimers, and mixtures thereof, of said olefin monomers, the improvement comprising said feed being further characterized by having from 1 to 100 ppm by volume sulfur-containing compounds and increasing the reaction temperature with time the catalyst is on stream.