US 7,541,408 B2
Curable resin composition, curable film and cured film
Daisuke Ohno, Tokyo (Japan); Kenji Ishii, Tokyo (Japan); and Yasumasa Norisue, Tokyo (Japan)
Assigned to Mitsubishi Gas Chemical Company, Inc., Tokyo (Japan)
Filed on Aug. 16, 2005, as Appl. No. 11/204,320.
Claims priority of application No. 2004/239068 (JP), filed on Aug. 19, 2004; and application No. 2005/194942 (JP), filed on Jul. 04, 2005.
Prior Publication US 2006/0041068 A1, Feb. 23, 2006
Int. Cl. C08L 53/02 (2006.01)
U.S. Cl. 525—88  [525/92 D; 525/98; 525/99] 7 Claims
 
1. A curable resin composition consisting of a high molecular weight compound having a weight average molecular weight of 70,000 to 300,00 and a vinyl compound of the formula (1),

OG Complex Work Unit Drawing
wherein the high molecular weight compound is at least one compound selected from the group consisting of a styrene isoprene styrene copolymer, a hydrogenated styrene butadiene styrene copolymer, a hydrogenated styrene isoprene styrene copolymer and a hydrogenated styrene (butadiene/isoprene) styrene copolymer, wherein the styrene content in the high molecular weight compound is from 20 to 65% by weight and the weight ratio of the vinyl compound of the formula (1): the high molecular weight compound is 30:70 to 70:30,
R1, R2, R3, R4, R5, R6 and R7 are the same or different and represent a hydrogen atom, a halogen atom, an alkyl group or a halogenated alkyl group,
—(O—X—O)— represents a moiety of the formula (2) or the formula (3) or represents at least two kinds of moieties of the formula (2) and/or the formula (3),

OG Complex Work Unit Drawing
in which R8, R9, R10, R14 and R15 are the same or different and represent a halogen atom, an alkyl group having 6 or less carbon atoms or a phenyl group and R11, R12 and R13 are the same or different and represent a hydrogen atom, a halogen atom, an alkyl group having 6 or less carbon atoms or a phenyl group,

OG Complex Work Unit Drawing
in which R16, R17, R22 and R23 are the same or different and represent a halogen atom, an alkyl group having 6 or less carbon atoms or a phenyl group, R18, R19, R20 and R21 are the same or different and represent a hydrogen atom, a halogen atom, an alkyl group having 6 or less carbon atoms or a phenyl group and A is a linear, branched or cyclic hydrocarbon having 20 or less carbon atoms,
—(Y—O)— represents a moiety of the formula (4) or a random arrangement of at least two kinds of moieties of the formula (4),

OG Complex Work Unit Drawing
in which R24 and R25 are the same or different and represent a halogen atom, an alkyl group having 6 or less carbon atoms or a phenyl group and R26 and R27 are the same or different and represent a hydrogen atom, a halogen atom, an alkyl group having 6 or less carbon atoms or a phenyl group,
Z represents an organic group having at least one carbon atom which may contain an oxygen atom, a nitrogen atom, a sulfur atom and/or a halogen atom,
each of a and b is an integer of from 0 to 30, provided that at least one of a and b is not 0, and each of c and d is an integer of 0 or 1.