US 7,537,748 B2
Hydrogen storage matter and manufacturing method and apparatus for the same
Hironobu Fujii, Hiroshima (Japan); Takayuki Ichikawa, Hiroshima (Japan); Haiyan Leng, Hiroshima (Japan); Shigehito Isobe, Hiroshima (Japan); Nobuko Hanada, Hiroshima (Japan); Toyoyuki Kubokawa, Chiba (Japan); Kazuhiko Tokoyoda, Chiba (Japan); Keisuke Okamoto, Chiba (Japan); Shinkichi Tanabe, Chiba (Japan); Shigeru Matsuura, Chiba (Japan); and Kenji Ogawa, Chiba (Japan)
Assigned to National University Corporation, Hiroshima University, Hiroshima (Japan); and Taiheiyo Cement Corporation, Tokyo (Japan)
Filed on Feb. 09, 2006, as Appl. No. 11/351,244.
Application 11/351244 is a continuation of application No. PCT/JP2004/009538, filed on Jul. 05, 2004.
Claims priority of application No. 2003-291672 (JP), filed on Aug. 11, 2003; application No. 2003-362943 (JP), filed on Oct. 23, 2003; application No. 2004-036967 (JP), filed on Feb. 13, 2004; application No. 2004-086925 (JP), filed on Mar. 24, 2004; application No. 2004-101759 (JP), filed on Mar. 31, 2004; application No. 2004-101948 (JP), filed on Mar. 31, 2004; application No. 2004-144850 (JP), filed on May 14, 2004; application No. 2004-186449 (JP), filed on Jun. 24, 2004; and application No. 2004-186450 (JP), filed on Jun. 24, 2004.
Prior Publication US 2006/0127304 A1, Jun. 15, 2006
Int. Cl. B01J 20/04 (2006.01); B01J 20/30 (2006.01)
U.S. Cl. 423—413  [423/646; 423/647; 423/658.2] 22 Claims
OG exemplary drawing
 
1. A hydrogen storage matter containing at least a nano-structured and organized lithium imide compound precursor complex,
wherein the lithium imide compound precursor complex has been nano-structured and organized by mixing fine powder lithium amide with fine powder lithium hydride at a predetermined ratio to prepare a mixture as a starting material, and then processing the mixture by a predetermined complex formation processing method, and the lithium imide compound precursor complex further comprises, as a catalyst to enhance a hydrogen absorption and release function, one or more of metal simple substances selected from the group consisting of C, B, Mg, V, Ti, Cr, Mn, Fe, Co, Ni, Cu, Zn, Zr, Ru, Rh, Pd, Pt, In, La and Nd, or one or more of alloys or compounds thereof, and has been formed by subjecting a mixture of the fine powder lithium hydride, the fine powder lithium amide, and the catalyst to a mechanical milling process in which the mixture is subjected to repeated microscopic collisions with crushing medium in an atmosphere of an inert gas, hydrogen gas, or nitrogen gas, or a mixed atmosphere thereof.