US 7,531,664 B2
Flame retarding compounds
Malisa V. Troutman, New York, N.Y. (US); Ramanathan Ravichandran, Suffern, N.Y. (US); Redina Kote, Peekskill, N.Y. (US); and Roswell E. King, Pleasantville, N.Y. (US)
Assigned to Ciba Specialty Chemicals Corporation, Tarrytown, N.Y. (US)
Filed on Apr. 12, 2005, as Appl. No. 11/104,057.
Application 11/104057 is a division of application No. 10/320155, filed on Dec. 16, 2002, granted, now 6,967,252.
Claims priority of provisional application 60/342331, filed on Dec. 21, 2001.
Claims priority of provisional application 60/416556, filed on Oct. 07, 2002.
Prior Publication US 2006/0135659 A1, Jun. 22, 2006
Int. Cl. C07D 211/08 (2006.01); C08K 5/3477 (2006.01)
U.S. Cl. 546—192  [524/101] 5 Claims
 
1. A compound of formula I

OG Complex Work Unit Drawing
where
R is hydrogen or methyl,
G1 and G2 are independently alkyl of 1 to 4 carbon atoms or are together pentamethylene,
x, y and z are each independently greater than or equal to 1,
L is independently of each other a direct bond or a hydrocarbylene group,
Z1 is hydrogen or hydrocarbyl, or is —OR1, —OCOR1, —COOR1, —CONR1R2, —NR1COR2, —COR1 or —NR1R2,
R1 and R2 are independently of each other hydrogen or hydrocarbyl, or R1 and R2 together form a hydrocarbylene group,
E is oxyl, hydroxyl, alkoxy, cycloalkoxy, aralkoxy, aryloxy, —O—CO—OG, —O—Si(G)3, or —O—CH2—OG where G is selected from the group consisting of hydrogen, an aliphatic, araliphatic and aromatic moiety; or E is —O-T-(OH)b,
T is a straight or branched chain alkylene of 1 to 18 carbon atoms, cycloalkylene of 5 to 18 carbon atoms, cycloalkenylene of 5 to 18 carbon atoms, a straight or branched chain alkylene of 1 to 4 carbon atoms substituted by phenyl or by phenyl substituted by one or two alkyl groups of 1 to 4 carbon atoms,
b is 1, 2 or 3 with the proviso that b cannot exceed the number of carbon atoms in T, and when b is 2 or 3, each hydroxyl group is attached to a different carbon atoms of T, and
FRM is independently of each other a flame retardant moiety selected from the group consisting of

OG Complex Work Unit Drawing
wherein T1 and T2 are independently alkyl, aryl, alkoxy, aralkoxy or dialkylamino; or said alkyl, aryl, alkoxy, aralkoxy or dialkylamino substituted by 1 to 8 halogen atoms;

OG Complex Work Unit Drawing
where one of the open bonds may be bonded to T1, defined above;

OG Complex Work Unit Drawing
where one of the open bonds may be bonded to T1, defined above;

OG Complex Work Unit Drawing
where one to three of the open bonds may be bonded to T1, defined above;

OG Complex Work Unit Drawing
where one to three of the open bonds may be bonded to T1, defined above;

OG Complex Work Unit Drawing
where one to three of the open bonds may be bonded to T1, defined above;

OG Complex Work Unit Drawing
where one of the open bonds may be bound to alkyl or aryl; or said alkyl or aryl substituted by 1 to 8 halogen atoms;

OG Complex Work Unit Drawing
where one of the open bonds may be bound to alkyl or aryl; or said alkyl or aryl substituted by 1 to 8 halogen atoms;

OG Complex Work Unit Drawing
where X is chlorine or bromine; and where one of the open bonds may be bonded to T1, defined above;
and
-(phosphazene flame retardant).