US 7,531,478 B2
Production of supported olefin polymerisation catalysts
Peter Denifl, Gries am Brenner (Austria); Erik Van Praet, Västra Frolunda (Sweden); and Michael Bartke, Järvenpää (Finland)
Assigned to Borealis Technology OY, Porvoo (Finland)
Appl. No. 10/499,761
PCT Filed Dec. 18, 2002, PCT No. PCT/EP02/14460
§ 371(c)(1), (2), (4) Date Feb. 04, 2005,
PCT Pub. No. WO03/051514, PCT Pub. Date Jun. 26, 2003.
Claims priority of application No. 01660237 (EP), filed on Dec. 19, 2001.
Prior Publication US 2005/0119113 A1, Jun. 02, 2005
This patent is subject to a terminal disclaimer.
Int. Cl. B01J 37/00 (2006.01); B01J 31/00 (2006.01); C08F 4/02 (2006.01); C08F 4/60 (2006.01)
U.S. Cl. 502—103  [502/104; 502/118] 62 Claims
 
1. A process for producing a supported olefin polymerization catalyst comprising a compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC), comprising suspending a porous particulate support material in a liquid/liquid at least two phase system which comprises a solution of one or more catalyst components in an organic solvent selected from linear, branched or cyclic alkane or alkene, an aromatic hydrocarbon and/or a halogen containing hydrocarbon or a mixture thereof and a solvent immiscible therewith, to impregnate said solution into the pores of said support material, wherein the active transition metal concentration in the support is from 0.001 to 10% by weight of the dry catalyst system, wherein the solution impregnated in said support particles is subjected to solidification to solidify the catalyst components and wherein said immiscible solvent which forms the continuous phase comprises a fluorinated hydrocarbon, a functionalized derivative thereof, or a mixture thereof.