| US 7,528,531 B2 | ||
| Piezoelectric ceramic composition and laminated piezoelectric element | ||
| Kumiko Iezumi, Tokyo (Japan); Junichi Yamazaki, Tokyo (Japan); and Norimasa Sakamoto, Tokyo (Japan) | ||
| Assigned to TDK Corporation, Tokyo (Japan) | ||
| Filed on Nov. 26, 2007, as Appl. No. 11/944,808. | ||
| Claims priority of application No. 2006-324770 (JP), filed on Nov. 30, 2006; and application No. 2006-324772 (JP), filed on Nov. 30, 2006. | ||
| Prior Publication US 2008/0129155 A1, Jun. 05, 2008 | ||
| Int. Cl. H01L 41/083 (2006.01); H01L 41/18 (2006.01) | ||
| U.S. Cl. 310—358 [310/363; 252/62.9 PZ] | 3 Claims |

| 1. A piezoelectric ceramic composition comprising:
a composite oxide, as a main component thereof, represented by the following composition formula (1) or (2);
Cu as a first additive, in a content α, in terms of Cu2O, falling within a range 0<α≤0.5% by mass in relation to said main component;
at least one selected from Li, Co, Ni, Ga and Mg, as a second additive, in a content β, in terms of carbonate for Li, falling
within a range 0<β≤0.1% by mass, in a content δ1, in terms of oxide for Co, Ni and Ga, falling within a range 0<δ1≤0.2% by
mass, and in a content δ2, in terms of carbonate for Mg, falling within a range 0≤δ2≤0.2% by mass in relation to said main
component; and
at least one selected from Ta, Nb, W and Sb, as a third additive, in a content γ, in terms of oxide, falling within a range
0<γ≤0.6% by mass in relation to said main component;
wherein:
Pba[(Zn1/3Nb2/3)xTiyZrz]O3, composition formula (1)
a, x, y and z in the composition formula (1) satisfying the following relations, 0.96≤a≤1.03, 0.005≤x≤0.047, 0.42≤y≤0.53,
0.45≤z≤0.56, and x+y+z=1; and
(Pba-bMeb)[(Zn1/3Nb2/3)xTiyZrz]O3, composition formula (2)
a, b, x, y and z in the composition formula (2) satisfying the following relations, 0.96≤a≤1.03, 0≤b≤0.1, 0.005≤x≤0.047, 0.42≤y≤0.53,
0.45≤z≤0.56, and x+y+z=1, and Me in the composition formula (2) representing at least one selected from Sr, Ca and Ba.
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