US 7,528,531 B2
Piezoelectric ceramic composition and laminated piezoelectric element
Kumiko Iezumi, Tokyo (Japan); Junichi Yamazaki, Tokyo (Japan); and Norimasa Sakamoto, Tokyo (Japan)
Assigned to TDK Corporation, Tokyo (Japan)
Filed on Nov. 26, 2007, as Appl. No. 11/944,808.
Claims priority of application No. 2006-324770 (JP), filed on Nov. 30, 2006; and application No. 2006-324772 (JP), filed on Nov. 30, 2006.
Prior Publication US 2008/0129155 A1, Jun. 05, 2008
Int. Cl. H01L 41/083 (2006.01); H01L 41/18 (2006.01)
U.S. Cl. 310—358  [310/363; 252/62.9  PZ] 3 Claims
OG exemplary drawing
 
1. A piezoelectric ceramic composition comprising:
a composite oxide, as a main component thereof, represented by the following composition formula (1) or (2);
Cu as a first additive, in a content α, in terms of Cu2O, falling within a range 0<α≤0.5% by mass in relation to said main component;
at least one selected from Li, Co, Ni, Ga and Mg, as a second additive, in a content β, in terms of carbonate for Li, falling within a range 0<β≤0.1% by mass, in a content δ1, in terms of oxide for Co, Ni and Ga, falling within a range 0<δ1≤0.2% by mass, and in a content δ2, in terms of carbonate for Mg, falling within a range 0≤δ2≤0.2% by mass in relation to said main component; and
at least one selected from Ta, Nb, W and Sb, as a third additive, in a content γ, in terms of oxide, falling within a range 0<γ≤0.6% by mass in relation to said main component;
wherein:
Pba[(Zn1/3Nb2/3)xTiyZrz]O3,  composition formula (1)
a, x, y and z in the composition formula (1) satisfying the following relations, 0.96≤a≤1.03, 0.005≤x≤0.047, 0.42≤y≤0.53, 0.45≤z≤0.56, and x+y+z=1; and
(Pba-bMeb)[(Zn1/3Nb2/3)xTiyZrz]O3,  composition formula (2)
a, b, x, y and z in the composition formula (2) satisfying the following relations, 0.96≤a≤1.03, 0≤b≤0.1, 0.005≤x≤0.047, 0.42≤y≤0.53, 0.45≤z≤0.56, and x+y+z=1, and Me in the composition formula (2) representing at least one selected from Sr, Ca and Ba.