| US 7,528,212 B2 | ||
| Ionizing radiation stable thermoplastic composition, method of making, and articles formed therefrom | ||
| Brian Mullen, Mt. Vernon, Ind. (US) | ||
| Assigned to SABIC Innovative Plastics IP B.V., Bergen op Zoom (Netherlands) | ||
| Filed on Nov. 18, 2005, as Appl. No. 11/282,377. | ||
| Prior Publication US 2007/0117957 A1, May 24, 2007 | ||
| Int. Cl. C08G 63/00 (2006.01) | ||
| U.S. Cl. 528—190 [250/472.1; 250/474.1; 264/176.1; 264/219; 428/411.1; 428/412] | 26 Claims |
| 1. A thermoplastic composition comprising:
a polycarbonate that is not aryl carboxylate end-capped, and
an aryl carboxylate end-capped polycarbonate of formula:
Ar1—C(O)—O-(-L-)m-O—C(O)—Ar1
wherein each Ar1 is independently an aryl group, -(-L-)m- is a polycarbonate linking group with m units of linking unit L, wherein L consists essentially of carbonate units wherein
m is at least one, or a combination of carbonate units with poly(arylene ether) units, soft block units, or a combination
comprising at least one of these, wherein m is 2 to 500 and at least one L is a carbonate unit;
wherein the aryl carboxylate end-capped polycarbonate has aryl carboxylate end groups present in the thermoplastic composition
in an amount of 0.01 to 500 mmol/Kg based on the combined weights of the polycarbonate that is not aryl carboxylate end-capped,
and the aryl carboxylate end-capped polycarbonate, and
wherein a molded article having a thickness of 3.2±0.12 millimeters and consisting of the aryl carboxylate end-capped polycarbonate,
the polycarbonate that is not aryl carboxylate end-capped, and less than or equal to 1.0 percent total weight of aliphatic
diol, a mold-release agent, and an antioxidant has, after exposure to a total gamma radiation dose of 81 kGy and when measured
according to ASTM D1925-70, an increase in yellowness index (dYI) of less than or equal to 24.5, when compared to the unexposed
molded article.
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