| US 7,514,498 B2 | ||
| Films or structural exterior materials using coating composition having self-cleaning property and preparation method thereof | ||
| Yang Gu Kang, Daejeon (Korea, Republic of); Seung Heon Lee, Daejeon (Korea, Republic of); Young Jun Hong, Daejeon (Korea, Republic of); Jung Hoon Kim, Cheongju-si (Korea, Republic of); Hye Jeong Lee, Suwon-si (Korea, Republic of); Sang Ho Shin, Cheongju-si (Korea, Republic of); Sung Hoon Jang, Daejeon (Korea, Republic of); Hong Cheul Shin, Seoul (Korea, Republic of); Yeong Rae Chang, Daejeon (Korea, Republic of); and Yeon Bin Lee, Seoul (Korea, Republic of) | ||
| Assigned to LG Chem Ltd., Seoul (Korea, Republic of) | ||
| Filed on Jul. 01, 2005, as Appl. No. 11/171,326. | ||
| Claims priority of application No. 10-2004-0073799 (KR), filed on Sep. 15, 2004; and application No. 10-2005-0033621 (KR), filed on Apr. 22, 2005. | ||
| Prior Publication US 2006/0058490 A1, Mar. 16, 2006 | ||
| Int. Cl. C08L 83/00 (2006.01); C08L 83/02 (2006.01); B32B 9/00 (2006.01); C09D 183/04 (2006.01) | ||
| U.S. Cl. 524—588 [524/859; 428/447; 106/287.16] | 10 Claims |

| 1. A coating composition having self-cleaning property comprising:
(a) 1-15 wt % of first inorganic particles that contain hydroxy group and have an average particle diameter of between 5 and
30 nm;
(b) 0.05-3 wt % of second inorganic particles that contain hydroxy group and have an average particle diameter of between
0.2 and 5 μm;
(c) 1-15 wt % of an organosilane compound represented by the following formula (1);
(d) 50-85 wt % of a solvent;
(e) 0.1-3 wt % of photocatalyst particles;
(f) 1-10 wt % of the hydrolyzate of alkoxysilane-functionalized aromatic UV absorbing agent represented by the following formula
(2);
(g) 0.001-2 wt % of an acid;
(h) 1-10 of a heat curling catalyst; and
(i) 1-10 wt % of aqueous polyurethane emulsion;
RnSi(OR′)4-n(I) [Formula 1]
wherein R is a C1-C8 aminoalkyl group, glycidoxyalkyl group or isocyanatoalkyl group;
R′ is a C1-C6 lower alkyl group; and
n is an integer of between 0 and 3;
![]() wherein R1 and R2 independently represent a C1-C6 alkyl group;
R3 represents a C1-C6 alkyl group or aryl group;
OR4 represents a methoxy, ethoxy, propoxy, isopropoxy, butoxy or acetoxy group;
R5 represents a C1-C12 alkyl group or aryl group;
X represents a hydrogen atom or halogen atom;
l is an integer of between 5 and 9;
m is an integer of between 1 and 3; and
n is an integer of between 0 and 2.
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