US 7,514,392 B2
Shale hydration inhibition agent and method of use
Arvind D. Patel, Sugarland, Tex. (US); and Emanuel Stamatakis, Houston, Tex. (US)
Assigned to M-I L.L.C., Houston, Tex. (US)
Filed on May 06, 2005, as Appl. No. 11/123,394.
Application 11/123394 is a continuation in part of application No. 10/958635, filed on Oct. 05, 2004, granted, now 7,312,183.
Prior Publication US 2006/0073983 A1, Apr. 06, 2006
Int. Cl. C09K 8/035 (2006.01)
U.S. Cl. 507—239  [507/129; 507/248] 4 Claims
 
1. A water-base well bore fluid for use in a subterranean well penetrating through one or more subterranean formations containing a shale which swells in the presence of water, wherein the fluid comprises:
an aqueous based continuous phase;
a weighting agent; and
a shale hydration inhibition agent having the formula:

OG Complex Work Unit Drawing
in which R and R′ independently selected from hydrogen, methyl, ethyl or propyl, R″ is a bridging group having 1 to 20 carbon atoms and n has a value from 1 to 4 and X is an amine, hydroxyl, alkoxy, carboxy group, in which at least one of the amine functional groups have been reacted with a predetermined amount of C1 to C25 carboxylic acid; and
wherein the concentration of shale hydration inhibition agent is from about 0.5 to about 20 pounds per barrel of the water base well bore fluid.