| US 7,511,084 B2 | ||
| Acyl- and bisacylphosphine derivatives | ||
| Ralf Noe, Mannheim (Germany); Andreas Henne, Neustadt (Germany); and Matthias Maase, Speyer (Germany) | ||
| Assigned to BASF Aktiengesellschaft, Ludwigshafen (Germany) | ||
| Appl. No. 10/502,658 PCT Filed Feb. 04, 2003, PCT No. PCT/EP03/01053 § 371(c)(1), (2), (4) Date Aug. 04, 2004, PCT Pub. No. WO03/068784, PCT Pub. Date Aug. 21, 2003. |
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| Claims priority of application No. 102 06 117 (DE), filed on Feb. 13, 2002. | ||
| Prior Publication US 2005/0222294 A1, Oct. 06, 2005 | ||
| Int. Cl. C08F 2/46 (2006.01) | ||
| U.S. Cl. 522—64 [522/28; 522/30; 522/7] | 19 Claims |
1. An acyl- or bisacylphosphine derivative of the formula (I)
![]() R1 is α-naphthyl, β-naphthyl, 2-, 3- or 4-chlorophenyl, 2,6- or 2,4-dichlorophenyl, 2,4,6-trichlorophenyl, 2-, 3- or 4-methylphenyl,
2,6- or 2,4-dimethylphenyl, 2,4,6-trimethylphenyl, 2-, 3- or 4-ethylphenyl, 2,6- or 2,4-diethylphenyl, 2-, 3- or 4-iso-propylphenyl,
2-, 3- or 4-tert-butylphenyl, 2-, 3- or 4-methoxyphenyl, 2,6- or 2,4-dimethoxyphenyl, 2,6- or 2,4-diethoxyphenyl, methylnaphthyl,
2,6-dimethylphenyl, 2,4,6-trimethylphenyl, 2,6-dimethoxyphenyl, 2,6-dichlorophenyl, 4-bromophenyl, 2- or 4-nitrophenyl, 2,4-or
2,6-dinitrophenyl, 4-dimethylaminophenyl, 4-acetylphenyl, cyclopentyl, cyclohexyl, 2,5-dimethylcyclopentyl, 2,6-dimethylcyclohexyl,
2,6-diethylcyclohexyl, 2,6-dimethoxycyclohexyl, 2,6-diethoxycyclohexyl, 2,6-dichlorocyclohexyl, 2,5-dichlorocyclopentyl, 2-
or 3-furyl, 2- or 3-thiophenyl, 2- or 3-pyrryl, dimethylpyrryl or an ortho-substituted phenyl other than 2-methylphenyl, 2-methoxyphenyl
or 2-chlorophenyl,
R2, R5, R6 and R7 are C1-C18-alkyl, or C2-C18-alkyl, C2-C18-alkenyl, C6-C12-aryl or C5-C12-cycloalkyl, each of which is uninterrupted or interrupted by one or more oxygen and/or sulfur atoms and/or one or more substituted
or unsubstituted imino groups, or are a five- to six-membered, oxygen, nitrogen and/or sulfur atom-containing heterocyclic
radical, where the said radicals may each be substituted by aryl, alkyl, aryloxy, alkoxy, heteroatoms and/or heterocyclic
radicals,
R2 is furthermore C1-C18-alkoxy, which is unsubstituted or substituted by aryl, alkyl, aryloxy, alkoxy, heteroatoms and/or heterocyclic radicals,
or is R1—(C═Y)—,
Y is O, S, NR3, N—OR3 or N—NR3R4,
Z is O, S, NR3, N—OR3, N—NR3R4 or a free pair of electrons,
R3 is hydrogen, C1- to C4-alkyl, SO3H, phenyl or acetyl,
R4 is hydrogen, C1- to C4-alkyl, COOR3, or C6-C12-aryl or arylsulfonyl, each of which is unsubstituted or substituted by aryl, alkyl, aryloxy, alkoxy, heteroatoms and/or heterocyclic
radicals,
FG is a leaving group having the structure —Cl, —CN, —OCN, —SCN, —N+R6R7R8, —O(CO)R5, —O(CO)OR5, —O(SO)Cl, —O(SO2)OR5, —O(SO2)R5 or —O(CO)Cl,
R5 is furthermore C1-C18-alkoxy, which is unsubstituted or substituted by aryl, alkyl, aryloxy, alkoxy, heteroatoms and/or heterocyclic radicals,
and
R8 is C1-C18-alkyl, which is unsubstituted or substituted by aryl, alkyl, aryloxy, alkoxy, heteroatoms and/or heterocyclic radicals, or
C2-C18-alkyl, which is uninterrupted or interrupted by one or more oxygen and/or sulfur atoms and/or one or more substituted or
unsubstituted imino groups.
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