US 7,338,718 B2
Zinc hot dip galvanized steel plate excellent in press formability and method for production thereof
Shoichiro Taira, Tokyo (Japan); Masaki Tada, Tokyo (Japan); Yoshiharu Sugimoto, Tokyo (Japan); Masayasu Nagoshi, Tokyo (Japan); Takashi Kawano, Tokyo (Japan); Etsuo Hamada, Tokyo (Japan); Satoru Ando, Tokyo (Japan); Shinji Ootsuka, Tokyo (Japan); and Masaaki Yamashita, Tokyo (Japan)
Assigned to JFE Steel Corporation, Tokyo (Japan)
Appl. No. 10/521,474
PCT Filed Oct. 17, 2003, PCT No. PCT/JP03/13281
§ 371(c)(1), (2), (4) Date Feb. 09, 2005,
PCT Pub. No. WO2004/094683, PCT Pub. Date Nov. 04, 2004.
Claims priority of application No. 2003-113938 (JP), filed on Apr. 18, 2003.
Prior Publication US 2005/0139291 A1, Jun. 30, 2005
Int. Cl. B32B 15/04 (2006.01); C23C 2/06 (2006.01); C23C 2/26 (2006.01)
U.S. Cl. 428—633  [428/632; 428/659; 428/687] 18 Claims
OG exemplary drawing
 
1. A hot-dip galvanized steel sheet comprising:
a plating layer consisting essentially of a η phase; and
an oxide layer disposed on a surface of the plating layer, said oxide layer having an average thickness of 10 nm or more; and
the oxide layer comprising a Zn-based oxide layer and an Al-based oxide layer, the Zn-based oxide layer having a Zn/Al atomic concentration ratio of more than 1 and the Al-based oxide layer having a Zn/Al atomic concentration ratio of less than 1,
wherein the Zn-based oxide layer has microirregularities; and
the microirregularities have a mean spacing (S) determined based on a roughness curve of 1,000 nm or less and an average roughness (Ra) of 100 nm or less.