| US 7,498,725 B2 | ||
| Piezoelectric ceramic composition and laminated piezoelectric element | ||
| Kumiko Iezumi, Tokyo (Japan); Junichi Yamazaki, Tokyo (Japan); and Norimasa Sakamoto, Tokyo (Japan) | ||
| Assigned to TDK Corporation, Tokyo (Japan) | ||
| Filed on Nov. 26, 2007, as Appl. No. 11/944,768. | ||
| Claims priority of application No. 2006-324769 (JP), filed on Nov. 30, 2006. | ||
| Prior Publication US 2008/0129154 A1, Jun. 05, 2008 | ||
| Int. Cl. H01L 41/083 (2006.01) | ||
| U.S. Cl. 310—358 [310/363; 252/62.9 R; 252/62.9 PZ] | 3 Claims |

| 1. A piezoelectric ceramic composition comprising:
a composite oxide, as a main component thereof, represented by the following composition formula (1) or (2);
Cu as a first additive, in a content α, in terms of Cu2O, falling within a range 0<α≤0.5% by mass in relation to said main component;
at least one selected from Dy, Nd, Eu, Gd, Tb, Ho and Er, as a second additive, in a content β, in terms of oxide, falling
within a range 0<β≤0.3% by mass, in relation to said main component; and
at least one selected from Ta, Nb, W and Sb, as a third additive, in a content γ, in terms of oxide, falling within a range
0<γ≤0.6% by mass in relation to said main component;
wherein:
Pba[(Zn1/3Nb2/3)xTiyZrz]O3, composition formula (1):
a, x, y and z in the composition formula (1) satisfying the following relations, 0.96≤a≤1.03, 0.005≤x≤0.047, 0.42≤y≤0.53,
0.45≤z≤0.56, and x+y+z=1; and
(Pba−bMeb)[(Zn1/3Nb2/3)xTiyZrz]O3, composition formula (2):
a, b, x, y and z in the composition formula (2) satisfying the following relations, 0.96≤a≤1.03, 0<b≤0.1, 0.005≤x≤0.047,
0.42≤y≤0.53, 0.45≤z≤0.56, and x+y+z=1, and Me in the composition formula (2) representing at least one selected from Sr, Ca
and Ba.
|