US 7,498,016 B2
Preparation of syngas for acetic acid synthesis by partial oxidation of methanol feedstock
Daniel Marcel Thiebaut, Lescar (France)
Assigned to Acetex (Cyprus) Limited, Limassol (Cyprus)
Appl. No. 11/569,592
PCT Filed Jun. 23, 2005, PCT No. PCT/CY2005/000001
§ 371(c)(1), (2), (4) Date Nov. 25, 2006,
PCT Pub. No. WO2006/005269, PCT Pub. Date Jan. 19, 2006.
Claims priority of provisional application 60/586547, filed on Jul. 09, 2004.
Prior Publication US 2007/0225384 A1, Sep. 27, 2007
Int. Cl. C01B 3/24 (2006.01); C01B 31/18 (2006.01); C07C 27/00 (2006.01)
U.S. Cl. 423—650  [423/418.2; 518/700; 518/702; 518/703; 518/704] 18 Claims
OG exemplary drawing
 
1. A method for preparing a hydrogen-rich stream and a carbon monoxide-rich stream, comprising:
reacting a methanol feed stream and oxygen, and optionally a temperature moderator, in a partial oxidation reactor to produce a syngas stream, wherein the partial oxidation reactor is catalyst-free and operated at a temperature between 1100° and 2000° C.;
separating the syngas stream into a carbon dioxide rich stream and a mixed stream containing hydrogen/carbon monoxide; and
separating the mixed stream into a hydrogen-rich stream and a carbon monoxide-rich stream.