US 7,494,759 B2
Positive resist compositions and process for the formation of resist patterns with the same
Hideo Hada, Kawasaki (Japan); Masaru Takeshita, Kawasaki (Japan); and Satoshi Yamada, Kawasaki (Japan)
Assigned to Tokyo Ohka Kogyo Co., Ltd., Kawasaki-shi (Japan)
Appl. No. 11/597,696
PCT Filed May 24, 2005, PCT No. PCT/JP2005/009450
§ 371(c)(1), (2), (4) Date Nov. 27, 2006,
PCT Pub. No. WO2005/116768, PCT Pub. Date Dec. 08, 2005.
Claims priority of application No. 2004-161881 (JP), filed on May 31, 2004; application No. 2004-161882 (JP), filed on May 31, 2004; application No. 2005-133205 (JP), filed on Apr. 28, 2005; and application No. 2005-133206 (JP), filed on Apr. 28, 2005.
Prior Publication US 2007/0224538 A1, Sep. 27, 2007
Int. Cl. G03F 7/00 (2006.01); G03F 7/004 (2006.01)
U.S. Cl. 430—270.1  [430/311; 430/330] 17 Claims
 
1. A positive resist composition, comprising:
a resin component (A) that exhibits increased alkali solubility under action of acid; and
an acid generator component (B) that generates acid on irradiation, wherein
said component (A) is a copolymer including a structural unit (a1) derived from a mono(α-lower alkyl)acrylate that contains an acid-dissociable, dissolution-inhibiting group, a structural unit (b1) derived from a mono(α-lower alkyl)acrylate that contains a lactone ring, and a structural unit (c1) derived from a poly(α-lower alkyl)acrylate represented by a general formula (1) below:

OG Complex Work Unit Drawing
(wherein, R represents a lower alkyl group or a hydrogen atom, R11 and R12 each represent, independently, a lower alkyl group, n represents an integer from 1 to 5, and A represents a bivalent to hexavalent organic group).