US 7,491,855 B2
Integrated process for the production of bisphenol A from cumene hydroperoxide
Pramod Shankar Kumbhar, Bangalore (India); Jegadeesh Thampi, Bangalore (India); Bharat Singh, Bangalore (India); John W. Fulmer, Mt. Vernon, Ind. (US); and Prashant Anil Tatake, Bangalore (India)
Assigned to Sabic Innovative Plastics IP B.V., Bergen op Zoom (Netherlands)
Filed on Jun. 04, 2003, as Appl. No. 10/250,114.
Prior Publication US 2004/0249224 A1, Dec. 09, 2004
Int. Cl. C07C 39/16 (2006.01)
U.S. Cl. 568—728  [568/798] 32 Claims
 
1. A method for production of bisphenol A comprising the steps of:
(a) cleaving cumene hydroperoxide in the presence of an acid clay catalyst to substantially convert the cumene hydroperoxide to a cleavage mass comprising phenol and acetone; and
(b) reacting the cleavage mass in the presence of a cation exchange resin catalyst comprising a cation exchange resin and a mercaptan or mercaptoalkanoic acid promoter to substantially convert the phenol and acetone in the cleavage mass to bisphenol A,
wherein the cleavage mass produced in step (a) is reacted in step (b) without intermediate purification.