US 7,491,317 B2
Desulfurization in turbulent fluid bed reactor
Paul F. Meier, Bartlesville, Okla. (US); Max W. Thompson, Sugar Land, Tex. (US); Victor G. Hoover, Pearl River, La. (US); and Guido R. Germana, Katy, Tex. (US)
Assigned to China Petroleum & Chemical Corporation, Beijing (China)
Filed on Jun. 07, 2005, as Appl. No. 11/147,045.
Prior Publication US 2006/0272984 A1, Dec. 07, 2006
Int. Cl. C10G 45/02 (2006.01)
U.S. Cl. 208—208R  [208/243; 208/244; 208/245; 208/246; 208/247; 208/248; 208/249; 208/250] 7 Claims
OG exemplary drawing
 
1. A desulfurization process comprising the steps of:
(a) contacting a hydrocarbon-containing fluid stream with finely divided solid sorbent particulates comprising a reduced-valence promoter metal component and zinc oxide in a fluidized bed reactor vessel under desulfurization conditions sufficient to remove sulfur from said hydrocarbon-containing fluid stream and convert at least a portion of said zinc oxide to zinc sulfide, thereby providing a desulfurized hydrocarbon-containing stream and sulfur-loaded sorbent particulates;
(b) simultaneously with step (a), contacting at least a portion of said hydrocarbon-containing stream and said sorbent particulates with a series of substantially horizontal, vertically spaced baffle groups comprising a plurality of substantially parallel baffles each presenting a generally V-shaped cross-section, thereby reducing axial dispersion in said fluidized bed reactor;
(c) contacting said sulfur-loaded sorbent particulates with an oxygen containing regeneration stream in a regenerator vessel under regeneration conditions sufficient to convert at least a portion of said zinc sulfide to zinc oxide, thereby providing regenerated sorbent particulates comprising an unreduced promoter metal component; and
(d) contacting said regenerated sorbent particulates with a hydrogen-containing reducing stream in a reducer vessel under reducing conditions sufficient to reduce said unreduced promoter metal component, thereby providing reduced sorbent particulates.