US 7,488,656 B2
Removal of charged defects from metal oxide-gate stacks
Eduard A. Cartier, New York, N.Y. (US); Matthew W. Copel, Yorktown Heights, N.Y. (US); Supratik Guha, Chappaqua, N.Y. (US); Richard A. Haight, Mahopac, N.Y. (US); Fenton R. McFeely, Ossining, N.Y. (US); and Vijay Narayanan, New York, N.Y. (US)
Assigned to International Business Machines Corporation, Armonk, N.Y. (US)
Filed on Apr. 29, 2005, as Appl. No. 11/119,310.
Prior Publication US 2006/0246740 A1, Nov. 02, 2006
Int. Cl. H01L 21/336 (2006.01)
U.S. Cl. 438—287  [438/142; 438/197; 438/584; 438/585; 438/591; 438/758; 438/778; 438/785] 10 Claims
OG exemplary drawing
 
1. A method of re-oxidizing a high k gate dielectric of a material stack useful as a pFET to substantially remove charged defects therefrom comprising:
exposing a material stack including a gate dielectric having a dielectric constant of about 4.0 or greater to dilute oxygen at a temperature from about 250° C. to about 450° C. for a time period from about 1 minute to about 24 hours, said dilute oxygen has a partial pressure of 100 Torr or less.