| US 7,485,686 B2 | ||
| Manufacturing method of polyolefin | ||
| Kazuhiro Yamamoto, Kanagawa (Japan); Kiyoshi Yukawa, Mie (Japan); Yasuhiro Kashiwagi, Kanagawa (Japan); and Yoichi Maeda, Mie (Japan) | ||
| Assigned to Japan Polypropylene Corporation, Tokyo (Japan) | ||
| Filed on Jul. 29, 2004, as Appl. No. 10/901,230. | ||
| Application 10/901230 is a continuation of application No. PCT/JP03/10337, filed on Aug. 14, 2003. | ||
| Claims priority of application No. 2002-238179 (JP), filed on Aug. 19, 2002; and application No. 2002-338580 (JP), filed on Nov. 21, 2002. | ||
| Prior Publication US 2005/0032993 A1, Feb. 10, 2005 | ||
| Int. Cl. C08F 4/52 (2006.01); C08F 2/00 (2006.01) | ||
| U.S. Cl. 526—160 [526/170; 526/71; 526/59; 526/943] | 14 Claims |
| 1. A method for producing a polyolefin comprising:
polymerizing an olefin with a single site catalyst in a reactor, while controlling the amount of a halogen-containing compound
that is not a catalyst component in said reactor such that the molar ratio of a halogen atom in the halogen-containing compound
to a transition metal in the single site catalyst is 0.8 or less, wherein the halogen-containing compound is derived from
at least one material added to said reactor and/or at least one material produced in said reactor, and said controlling comprises
assaying the amount of halogen atoms present in the reactor by at least one of the following three methods:
a. measuring the amount of the halogen atoms contained in the materials in advance, and assaying the amount of the halogen
atoms present in the reactor from the amount of each material introduced into the reactor,
b. assaying the amount of the halogen atoms present in the reactor after each material has been introduced into the reactor,
or after manufacturing conditions have become a steady-state in the case of continuous process, by directly sampling the halogen
atoms from the reactor, and
c. determining the amount of halogen atoms by sampling halogen atoms in the middle of the line circulating each material,
and assaying the amount of the halogen atoms introduced into the reactor from the balance of the amount of each material circulating
in the reactor and that discharged from the reactor.
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