US 7,473,810 B1
Method of dechlorinating organic compounds comprising vicinal chlorides
Michael Van Der Puy, Amherst, N.Y. (US); and Jingji Ma, West Seneca, N.Y. (US)
Assigned to Honeywell International Inc., Morristown, N.J. (US)
Filed on Oct. 12, 2007, as Appl. No. 11/871,348.
Int. Cl. C07C 19/08 (2006.01); C07C 17/25 (2006.01); C07C 17/10 (2006.01)
U.S. Cl. 570—230  [570/155; 570/156; 570/134; 570/153; 570/226] 11 Claims
 
1. A method for selectively preparing 2-chloropentafluoropropene comprising reacting 1,2,2-trichloro-1,1,3,3,3-pentafluoropropane with hydrogen in the presence of a noble metal catalyst supported on metallic support to produce 2-chloropentafluoropropene, wherein said catalytic dechlorination is conducted under conditions effective to result in a 1,2,2-trichloro-1,1,3,3,3-pentafluoropropane conversion of at least about 50% and a selectivity for 2-chloropentafluoropropene of at least about 70 mol. %.